Journal: Modern Chemistry & Applications PDF
Published: 18-Aug-15 Volume: 3 Issue: 3
DOI: 10.4172/2329-6798.1000163 ISSN: 2329-6798
Authors: Mahendra Kumar Trivedi, Alice Branton, Dahryn Trivedi, Gopal Nayak, Khemraj Bairwa and Snehasis Jana*
Citation: Trivedi MK, Branton A, Trivedi D, Nayak G, Bairwa K, et al. (2015) Fourier Transform Infrared and Ultraviolet-Visible Spectroscopic Characterization of Ammonium Acetate and Ammonium Chloride: An Impact of Biofield Treatment. Mod Chem appl 3:163. doi:10.4172/2329-6798.1000163
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Ammonium acetate and ammonium chloride are the white crystalline solid inorganic compounds having wide application in synthesis and analytical chemistry. The aim of present study was to evaluate the impact of biofield treatment on spectral properties of inorganic salt like ammonium acetate and ammonium chloride. The study was performed in two groups of each compound i.e., control and treatment. Treatment groups were received Mr. Trivedis biofield treatment. Subsequently, control and treated groups were evaluated using Fourier Transform Infrared (FT-IR) and Ultraviolet-Visible (UV-Vis) spectroscopy. FT-IR spectrum of treated ammonium acetate showed the shifting in wavenumber of vibrational peaks with respect to control. Like, the N-H stretching was shifted from 3024-3586 cm-1 to 3033-3606 cm-1, C-H stretching from 2826-2893 cm-1 to 2817-2881 cm-1, C=O asymmetrical stretching from 1660-1702 cm-1 to 1680-1714 cm-1, N-H bending from 1533-1563 cm-1 to 1506-1556 cm-1 etc. Treated ammonium chloride showed the shifting in IR frequency of three distinct oscillation modes in NH4 ion i.e., at ?1, 3010 cm-1 to 3029 cm-1; ?2, 1724 cm-1 to 1741 cm-1; and ?3, 3156 cm-1 to 3124 cm-1. The N-Cl stretching was also shifted to downstream region i.e., from 710 cm-1 to 665 cm-1 in treated ammonium chloride. UV spectrum of treated ammonium acetate showed the absorbance maxima (?max) at 258.0 nm that was shifted to 221.4 nm in treated sample. UV spectrum of control ammonium chloride exhibited two absorbance maxima (?max) i.e., at 234.6 and 292.6 nm, which were shifted to 224.1 and 302.8 nm, respectively in treated sample.
Overall, FT-IR and UV data of both compounds suggest an impact of biofield treatment on atomic level i.e., at force constant, bond strength, dipole moments and electron transition energy between two orbitals of treated compounds as compared to respective control.
FT-IR spectrum of biofield treated ammonium acetate showed the alteration in wavenumber of IR peaks assigned to N-H, C-H, C=O and C-O stretching as compared to control. Likewise, the biofield treated ammonium chloride showed the alteration in wavenumber of IR peaks assigned to three (?1, ?2, and ?3) out of four distinct internal oscillations of NH4 group as well as N-Cl stretching with respect of control. UV spectra of ammonium acetate and ammonium chloride showed the alteration in absorption maxima (?max) after biofield treatment as compared to respective control.
Altogether, the FT-IR results suggest an impact of biofield treatment on atomic level like dipole moment, force constant, bond strength, and flexibility of treated compounds with respect to control. Likely, the UV result suggests the impact of biofield treatment on bonding and nonbonding electron transition of treated compounds with respect to control.